σ- versus π-Activation of Alkynyl Benzoates Using B(C6F5)3

We have prepared a range of alkynyl benzoates in high yields and have investigated their reactivities with the strong Lewis acid B(C6F5)3. In such molecules both σ-activation of the carbonyl and π-activation of the alkyne are possible. In contrast to the reactivity of propargyl esters with B(C6F5)3 which proceed via 1,2-addition of the ester and B(C6F5)3 across the alkyne, the inclusion of an a...

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→ Σ π , Λ π and related strong coupling constant Zhi -

In this article, we calculate the strong coupling constant g among the decuplet baryons, the octet baryons and the pseudoscalar mesons in the heavy baryon chiral perturbation theory with the light-cone QCD sum rules, and study the strong decays Σ∗ → Λπ,Σπ. The numerical value of the strong coupling constant g is consistent with our previous calculation, the central values lead to small SU(3) br...

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Tuning Conductance in π-σ-π Single-Molecule Wires.

While the single-molecule conductance properties of π-conjugated and σ-conjugated systems have been well-studied, little is known regarding the conductance properties of mixed σ-π backbone wires and the factors that control their transport properties. Here we utilize a scanning tunneling microscope-based break-junction technique to study a series of molecular wires with π-σ-π backbone structure...

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→ Σ π , Λ π and related strong coupling constant

In this article, we calculate the strong coupling constant g among the decuplet baryons, the octet baryons and the pseudoscalar mesons in the heavy baryon chiral perturbation theory with the light-cone QCD sum rules, and study the strong decays Σ∗ → Λπ,Σπ. The numerical value of the strong coupling constant g is consistent with our previous calculation, the central values lead to a conservative...

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Fe b 20 09 Strong decays Σ ∗ → Σ π , Λ π and related strong coupling constant Zhi -

In this article, we calculate the strong coupling constant g among the decuplet baryons, the octet baryons and the pseudoscalar mesons in the heavy baryon chiral perturbation theory with the light-cone QCD sum rules, and study the strong decays Σ∗ → Λπ,Σπ. The numerical value of the strong coupling constant g is consistent with our previous calculation, the central values lead to small SU(3) br...

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σ- versus π-Activation of Alkynyl Benzoates Using B(C6F5)3

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